01 - Set oven to 400°F and allow to fully preheat.
02 - Blot chicken breasts dry with paper towels. Evenly season both sides with salt, black pepper, and garlic powder.
03 - In a shallow bowl, combine grated Parmesan, fine breadcrumbs, chopped parsley, and dried oregano. Press each chicken breast into mixture to coat both sides thoroughly.
04 - Heat olive oil in a large ovenproof skillet over medium-high heat. Sear coated chicken breasts for 2 to 3 minutes per side until golden brown.
05 - Transfer skillet to oven. Bake for 18 to 22 minutes, or until the internal temperature reaches 165°F.
06 - Meanwhile, blend roasted red bell peppers, garlic, olive oil, balsamic vinegar, smoked paprika, and seasoning in a blender or food processor until smooth.
07 - Taste sauce and adjust salt or pepper as needed. Gently warm in a small saucepan over low heat if desired.
08 - Arrange baked Parmesan-crusted chicken breasts on plates. Spoon red pepper sauce over each portion and garnish with additional parsley if desired.